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The greatest commercial use of the element is the production of sulfuric acid for sulfate and phosphate fertilizers, and other chemical processes. The element sulfur is used in matches, insecticides, and fungicides. Many sulfur compounds are odoriferous, and the smells of odorized natural gas, skunk scent, grapefruit, and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting eggs and other biological processes. Sulfur is an essential element for all life, but almost always in the form of organosulfur compounds or metal sulfides. Three amino acids (cysteine, cystine, and methionine) and two vitamins (biotin and thiamine) are organosulfur compounds. Many cofactors also contain sulfur including glutathione and thioredoxin and iron. Elemental sulfur is not common in higher forms of life, but is both a product and an oxidant for various bacteria. Spelling and etymology. The spelling sulfur appears toward the end of the Classical period. The parallel f~ph spellings continued in Britain until the 1. The IUPAC adopted the spelling sulfur in 1. Nomenclature Committee of the Royal Society of Chemistry in 1. Britain. The Spanish and Portuguese words are prefixed with the Arabic article, despite not being Arabic words. The point group of cyclo- S8 is D4d and its dipole moment is 0 D. Between its melting and boiling temperatures, octasulfur changes its allotrope again, turning from . Molten sulfur assumes a dark red color above 2. The density of sulfur is about 2 g. Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene and toluene. The first and second ionization energies of sulfur are 9. J. Despite such figures, the +2 oxidation state is rare, with +4 and +6 being more common. The fourth and sixth ionization energies are 4. J. Some of those reactions need elevated temperatures. X- ray crystallography studies show that the amorphous form may have a helical structure with eight atoms per turn. The long coiled polymeric molecules make the brownish substance elastic, and in bulk this form has the feel of crude rubber. This form is metastable at room temperature and gradually reverts to crystalline molecular allotrope, which is no longer elastic. This process happens within a matter of hours to days, but can be rapidly catalyzed. Isotopes. The differences between minerals can be used to estimate the temperature of equilibration. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydrologic studies. Differences in the natural abundances can be used in systems where there is sufficient variation in the 3. S of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have different . Ordinary chondrites contain on average 2. It is normally present as troilite (Fe. S), but there are exceptions, with carbonaceous chondrites containing free sulfur, sulfates and other sulfur compounds. Such deposits are polycrystalline, with the largest documented single crystal measuring 2. Native sulfur may be produced by geological processes alone. Fossil- based sulfur deposits from salt domes were until recently the basis for commercial production in the United States, Russia, Turkmenistan, and Ukraine. Such sources are now of secondary commercial importance, and most are no longer worked. Common naturally occurring sulfur compounds include the sulfide minerals, such as pyrite (iron sulfide), cinnabar (mercury sulfide), galena (lead sulfide), sphalerite (zinc sulfide) and stibnite (antimony sulfide); and the sulfates, such as gypsum (calcium sulfate), alunite (potassium aluminium sulfate), and barite (barium sulfate). On Earth, just as upon Jupiter's moon Io, elemental sulfur occurs naturally in volcanic emissions, including emissions from hydrothermal vents. Production. Then, some sulfur was pulverized, spread over the stacked ore and ignited, causing the free sulfur to melt down the hills. Eventually the surface- borne deposits played out, and miners excavated veins that ultimately dotted the Sicilian landscape with labyrinthine mines. Mining was unmechanized and labor- intensive, with pickmen freeing the ore from the rock, and mine- boys or carusi carrying baskets of ore to the surface, often through a mile or more of tunnels. Once the ore was at the surface, it was reduced and extracted in smelting ovens. The conditions in Sicilian sulfur mines were horrific, prompting Booker T. Today's sulfur production is as a side product of other industrial processes such as oil refining; in these processes, sulfur often occurs as undesired or detrimental compounds that are extracted and converted to elemental sulfur. As a mineral, native sulfur under salt domes is thought to be a fossil mineral resource, produced by the action of ancient bacteria on sulfate deposits. It was removed from such salt- dome mines mainly by the Frasch process. Throughout the 2. Due to a limited number of such sulfur deposits and the high cost of working them, this process for mining sulfur has not been employed in a major way anywhere in the world since 2. Organosulfur compounds, undesirable impurities in petroleum, may be upgraded by subjecting them to hydrodesulfurization, which cleaves the C. This process entails oxidation of some hydrogen sulfide to sulfur dioxide and then the comproportionation of the two. Countries producing more than 5 Mt are China (9. US (8. 8), Canada (7. Russia (7. 1). Sulfur forms stable compounds with all elements except the noble gases. Sulfur polycations. Bucholz, but the cause of the color and the structure of the polycations involved was only determined in the late 1. S8. 2+ is deep blue, S4. S1. 62+ is red. When dissolved in water, hydrogen sulfide is mildly acidic. Protonation of these polysulfide anions produces the polysulfanes, H2. Sx where x = 2, 3, and 4. Zig- zag (b) and straight (c) S chains inside double- wall CNTs. Sulfur dioxide and sulfites (SO2. Sulfur trioxide and sulfates (SO2. Sulfuric acid and SO3 combine to give oleum, a solution of pyrosulfuric acid (H2. S2. O7) in sulfuric acid. Thiosulfate salts (S2. O2. Sodium dithionite (Na. S2. O4), contains the more highly reducing dithionite anion (S2. O2. Sulfur hexafluoride is a dense gas used as an insulator gas in high voltage transformers; it is also a nonreactive and nontoxic propellant for pressurized containers. Sulfur tetrafluoride is rarely used organic reagent that and is highly toxic. Sulfuryl chloride and chlorosulfuric acid are derivatives of sulfuric acid; thionyl chloride (SOCl. Heating this compound gives polymeric sulfur nitride ((SN)x), which has metallic properties even though it does not contain any metal atoms. Thiocyanates contain the SCN. Oxidation of thiocyanate gives thiocyanogen, (SCN)2 with the connectivity NCS- SCN. Phosphorus sulfides are numerous, the most important commercially being the cages P4. S1. 0 and P4. S3. These materials tend to be dark- colored semiconductors that are not readily attacked by water or even many acids. They are formed, both geochemically and in the laboratory, by the reaction of hydrogen sulfide with metal salts. The mineral galena (Pb. S) was the first demonstrated semiconductor and was used as a signal rectifier in the cat's whiskers of early crystal radios. The iron sulfide called pyrite, the so- called . Sulfur corrodes many metals through tarnishing. Organic compounds. It is used as a reagent to make the polymer rayon and many organosulfur compounds. Unlike carbon monoxide, carbon monosulfide is stable only as an extremely dilute gas, found between solar systems. They are widely known as the odorant in domestic natural gas, garlic odor, and skunk spray. Not all organic sulfur compounds smell unpleasant at all concentrations: the sulfur- containing monoterpenoid (grapefruit mercaptan) in small concentrations is the characteristic scent of grapefruit, but has a generic thiol odor at larger concentrations. Sulfur mustard, a potent vesicant, was used in World War I as a disabling agent. In the most common type of industrial . This process, patented in 1. Because of the heat and sulfur, the process was named vulcanization, after the Roman god of the forge and volcanism. History. English translations of the Bible commonly referred to burning sulfur as . It is from this part of the Bible that Hell is implied to . According to the Ebers Papyrus, a sulfur ointment was used in ancient Egypt to treat granular eyelids. Sulfur was used for fumigation in preclassical Greece. He mentions its use for fumigation, medicine, and bleaching cloth. It remains an ingredient of black gunpowder. Indian alchemists, practitioners of . In traditional skin treatment, elemental sulfur was used (mainly in creams) to alleviate such conditions as scabies, ringworm, psoriasis, eczema, and acne. The mechanism of action is unknown. By the late 1. 8th century, about 2,0. Marseilles, France for the production of sulfuric acid by the Leblanc process. In industrializing Britain, with the repeal of tariffs on salt in 1. Sicily surged upward. Universal Remote Control PHILIPS MAGNAVOX PM6. S 6 Device Universal Learning Remote/magnavox- remote- control/5. Bwm! This is a GENUINE Magnavox Product! Part Numbers are RC7. RC7. 13. 9/1. 7 or 4. 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The New Deal, Then and Now. The great achievements of the New Deal helped pave. New Deal - Wikipedia. The New Deal was a series of social liberal programs enacted in the United States between 1. They included both laws passed by Congress as well as presidential executive orders during the first term (1. The programs were in response to the Great Depression, and focused on what historians refer to as the . The Republicans were split, with conservatives opposing the entire New Deal as an enemy of business and growth, and liberals accepting some of it and promising to make it more efficient. The realignment crystallized into the New Deal Coalition that dominated most presidential elections into the 1. Congress from 1. 93. As noted by Alexander Hicks, . The Federal Emergency Relief Administration provided $5. Civil Works Administration (CWA) gave localities money to operate make- work projects in 1. The controversial work of the National Recovery Administration was also part of the First New Deal. The . The final major items of New Deal legislation were the creation of the United States Housing Authority and Farm Security Administration, both in 1. Fair Labor Standards Act of 1. Conservative Republicans and Democrats in Congress joined in the informal Conservative Coalition. Roosevelt himself turned his attention to the war effort, and won reelection in 1. The Supreme Court declared the National Recovery Administration (NRA) and the first version of the Agricultural Adjustment Act (AAA) unconstitutional, however the AAA was rewritten and then upheld. As the first Republican president elected after FDR, Dwight D. Johnson's Great Society used the New Deal as inspiration for a dramatic expansion of liberal programs, which Republican Richard M. Nixon generally retained. After 1. 97. 4, however, the call for deregulation of the economy gained bipartisan support. The largest programs still in existence today are the Social Security System and the Securities and Exchange Commission (SEC). Origins. Unemployment in the U. S. In the aggregate, almost 5. New Deal Agencies Still in Effect Today by. It helped poor farmers by a variety of economic and educational programs. 1933: Effort to modernize very poor. Birth of the “New Deal' The concepts that became the New Deal had been discussed in earlier years but without effect. The New Deal programs were. This list features 7 of FDR’s New Deal 'alphabet soup' agencies that still exist. At that time there was no national safety net, no public unemployment insurance, and no Social Security. As Roosevelt took the oath of office at noon on March 4, 1. Americans had little or no access to their bank accounts. Farm income had fallen by over 5. Kennedy, Sr., who remained wealthy during the Depression, stated years later that . I pledge myself to a new deal for the American people. This is more than a political campaign. It is a call to arms. Her list of what her priorities would be if she took the job illustrates: . Assistant Attorney General Thurman Arnold led efforts that hearkened back to an anti- monopoly tradition rooted in American politics by figures such as Andrew Jackson and Thomas Jefferson. Supreme Court Justice Louis Brandeis, an influential adviser to many New Dealers, argued that . However, the anti- monopoly group never had a major impact on New Deal policy. Johnson of the NRA took ideas from the Woodrow Wilson Administration, advocating techniques used to mobilize the economy for World War I. They brought ideas and experience from the government controls and spending of 1. Other New Deal planners revived experiments suggested in the 1. TVA. The . The consequences were uneven. Some programs, especially the National Recovery Administration (NRA) and the silver program, have been widely seen as failures. The economy shot upward, with FDR's first term marking one of the fastest periods of GDP growth in history. Though a downturn in 1. The first organized opposition in 1. American Liberty League led by conservative Democrats such as 1. John W. There was also a large but loosely affiliated group of New Deal opponents, who are commonly called the Old Right. This group included politicians, intellectuals, writers, and newspaper editors of various philosophical persuasions including classical liberals and conservatives, both Democrats and Republicans. A number of leading Democrats, who were progressives of the Woodrow Wilson era, were also critical of Roosevelt's New Deal policies. Patterson, these leaders . They continued to believe that their party stood for Wilsonian ideals: regulated competition, states' rights, and individual freedom where it did not impinge upon the liberty of others. It especially led to greatly increased federal regulation of the economy. The effects of the New Deal remain a source of controversy and debate among economists and historians. They are typically known by their alphabetical initials. The First 1. 00 Days (1. Roosevelt entered office with enormous political capital. Americans of all political persuasions were demanding immediate action, and Roosevelt responded with a remarkable series of new programs in the . During those 1. 00 days of lawmaking, Congress granted every request Roosevelt asked, and passed a few programs (such as the FDIC to insure bank accounts) that he opposed. Ever since, presidents have been judged against FDR for what they accomplished in their first 1. Walter Lippmann famously noted: At the end of February we were a congeries of disorderly panic- stricken mobs and factions. In the hundred days from March to June we became again an organized nation confident of our power to provide for our own security and to control our own destiny. Economic indicators show the economy reached nadir in the first days of March, then began a steady, sharp upward recovery. Thus the Federal Reserve Index of Industrial Production sank to its lowest point of 5. July 1. 93. 2 (with 1. Recovery was steady and strong until 1. Except for employment, the economy by 1. The Recession of 1. Private sector employment, especially in manufacturing, recovered to the level of the 1. The act proposed to balance the . It saved $5. 00 million per year and reassured deficit hawks, such as Douglas, that the new President was fiscally conservative. Roosevelt argued there were two budgets: the . It was imbalanced on a temporary basis. Roosevelt strenuously opposed the Bonus Bill that would give World War I veterans a cash bonus. Congress finally passed it over his veto in 1. Treasury distributed $1. Most economists of the era, along with Henry Morgenthau of the Treasury Department, rejected Keynesian solutions and favored balanced budgets. See media help. At the beginning of the Great Depression the economy was destabilized by bank failures followed by credit crunches. The initial reasons were substantial losses in investment banking, followed by bank runs. As the bank run progressed, it generated a self- fulfilling prophecy: as more people withdrew their deposits, the likelihood of default increased, and this encouraged further withdrawals.) Milton Friedman and Anna Schwartz have argued that the drain of money out of the banking system caused the monetary supply to shrink, forcing the economy to likewise shrink. As credit and economic activity diminished, price deflation followed, causing further economic contraction with disastrous impact on banks. Roosevelt, however, gave a radio address, held in the atmosphere of a Fireside Chat, and explained to the public in simple terms the causes of the banking crisis, what the government will do and how the population could help. He closed all the banks in the country and kept them all closed until he could pass new legislation. The act was passed and signed into law the same day. It provided for a system of reopening sound banks under Treasury supervision, with federal loans available if needed. Three- quarters of the banks in the Federal Reserve System reopened within the next three days. Billions of dollars in hoarded currency and gold flowed back into them within a month, thus stabilizing the banking system. By the end of 1. 93. Their deposits totalled $3. It also established the Federal Deposit Insurance Corporation (FDIC), which insured deposits for up to $2,5. The Federal Reserve would have had to execute an expansionary monetary policy to fight the deflation and to inject liquidity into the banking system to prevent it from crumbling. Roosevelt stopped the outflow of gold by forbidding the export of gold except under license from the Treasury. Anyone holding significant amounts of gold coinage was mandated to exchange it for the existing fixed price of US dollars. The Treasury no longer paid out gold in exchange for dollars, and gold would no longer be considered valid legal tender for debts in private and public contracts. With the passage of the Gold Reserve Act in 1. These measures enabled the Federal Reserve to increase the amount of money in circulation to the level the economy needed. Markets immediately responded well to the suspension, in the hope that the decline in prices would finally end. Even firms whose securities were publicly traded published no regular reports or even worse rather misleading reports based on arbitrarily selected data. To avoid another Wall Street Crash the Securities Act of 1. It required the disclosure of the balance sheet, profit and loss statement, the names and compensations of corporate officers, about firms whose securities were traded. Additionally those reports had to be verified by independent auditors. Securities and Exchange Commission was established to regulate the stock market and prevent corporate abuses relating to the sale of securities and corporate reporting. He signed the bill to legalize the manufacture and sale of alcohol, an interim measure pending the repeal of Prohibition, for which a constitutional amendment of repeal (the 2. The repeal amendment was ratified later in 1. States and cities gained additional new revenue, and Roosevelt secured his popularity especially in the cities and ethnic areas by helping the beer start flowing. Also, relief was aimed at providing temporary help to suffering and unemployed Americans. Public works. Through reforestation and flood control, they reclaimed millions of hectares of soil from erosion and devastation. As noted by one authority, Roosevelt's New Deal . 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